Changes induced by UV radiation in the presence of sodium benzoate in films formulated with polyvinyl alcohol and carboxymethyl cellulose

This work was focused on: i) developing single and blend films based on carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVOH) studying their properties, ii) analyzing the interactions between CMC and PVOH and their modifications UV-induced in the presence of sodium benzoate (SB), and iii) evaluating the antimicrobial capacity of blend films containing SB with and without UV treatment. Once the blend films with SB were exposed to UV radiation, they exhibited lower moisture content as well as a greater elongation at break and rougher surfaces compared to those without treatment. Considering oxygen barrier properties, the low values obtained would allow their application as packaging with selective oxygen permeability. Moreover, the characteristics of the amorphous phase of the matrix prevailed with a rearrangement of the structure of the polymer chain, causing a decrease of the crystallinity degree. These results were supported by X-rays and DSC analysis. FT-IR spectra reflected some degree of polymer–polymer interaction at a molecular level in the amorphous regions. The incorporation of sodium benzoate combined with UV treatment in blend films was positive from the microbial point of view because of the growth inhibition of a wide spectrum of microorganisms. From a physicochemical perspective, the UV treatment of films also changed their morphology rendering them more insoluble in water, turning the functionalized blend films into a potential material to be applied as food packaging.Fil: Villarruel, S.. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; ArgentinaFil: Giannuzzi, Leda. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaFil: Rivero, Sandra G. M.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaFil: Pinotti, Adriana Noemi. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentin

Holography, Heavy-Quark Free Energy, and the QCD Phase Diagram

We use gauge/string duality to investigate the free energy of two static color sources (a heavy quark-antiquark pair) in a Yang-Mills theory in strongly interacting matter, varying temperature and chemical potential. The dual space geometry is Anti-de Sitter with a charged black-hole to describe finite temperature and density in the boundary theory, and we also include a background dilaton field to generate confinement. The resulting phase diagram in the chemical potential-temperature $\mu-T$ plane is in a quite good agreement with lattice results and effective models of QCD.Comment: 4 pages, 5 figures, version published on PR

Thermal characterization methodology for dry finishing turning of SAF 2507 stainless steel based on finite element simulations and surrogate models

This paper addresses the numerical thermal characterization of a 3D turning process of a SAF 2507 stainless steel. A thermographic test campaign was conducted to measure the temperature distribution at the tool-workpiece interface. The campaign was accommodated by means of a L18 fractional factorial design of experiment. The 3D turning process was simulated using the software TWS Advantedge. The heat transfer numerical coefficients were calibrated against experimental measures to obtain temperature values as accurate as possible. A statistical methodology framework was adopted to study the dependence of the coefficients from the machining parameters. A heat transfer surrogate model was then built and next experimentally validated

IC.IDO as a tool for displaying machining processes. The logic interface between computer-aided-manufacturing and virtual reality

This scientific communication investigates the logic interface of a CAM solver, i.e., MasterCAM, into a Virtual Reality (VR) environment. This integration helps in displaying machining operations in virtual reality. Currently, to partially visualize the results of a simulation in an immersive environment, an import/export procedure must be done manually. Here, a software plugin integrated into IC.IDO (by ESI Group) has been realized and fully described. This application allows the complete integration of CAM solver into the VR environment. In particular, the VERICUT solver has been integrated into VR. This kind of integration has never been done yet

Explosive-driven shock wave and vortex ring interaction with a propane flame

Experiments were performed to analyze the interaction of an explosively driven shock wave and a propane flame. A 30 g explosive charge was detonated at one end of a 3-m-long, 0.6-m-diameter shock tube to produce a shock wave which propagated into the atmosphere. A propane flame source was positioned at various locations outside of the shock tube to investigate the effect of different strength shock waves. High-speed retroreflective shadowgraph imaging visualized the shock wave motion and flame response, while a synchronized color camera imaged the flame directly. The explosively driven shock tube was shown to produce a repeatable shock wave and vortex ring. Digital streak images show the shock wave and vortex ring propagation and expansion. The shadowgrams show that the shock wave extinguishes the propane flame by pushing it off of the fuel source. Even a weak shock wave was found to be capable of extinguishing the flame

Il sistema NILDE per il Document Delivery: dalla sperimentazione alla cooperazione, dal progetto al servizio

NILDE: dalla nascita del progetto nella Biblioteca di Area del CNR di Bologna allo sviluppo di un servizio basato su parametri qualitativi e su di un metodo di lavoro cooperativo tra biblioteche universitarie, di enti di ricerca e pubbliche presenti sul territorio nazionale. Le motivazioni che hanno portato alla sottoscrizione di un Regolamento condiviso da tutte le biblioteche aderenti e l\u27esperienza di tre anni di cooperazione

Validation of TiAlN functional coatings through cryo-tribological characterization using a pin-on-disk experiment

Abstract The purpose of this study has been to investigate the effects of TiAlN functional coatings in cryo-tribological pin-on-disk experiments. Nowadays, the introduction of new machining technologies for chip removal, both at high speed and in cryogenic conditions, is posing new challenges and opening new horizons to research. As a matter of fact, that in this technology needs to focus on the choice of workpiece materials to be machining and tools coatings used. For the latter, the wear phenomenon has been studied employing pins-on-disk (made by nickel-based alloys) under a liquid nitrogen jet flows simulating cryogenic machining. The coatings used have been of two different types: the coating C1 is a ZrTiAlN quaternary, while the coating C2 is a TiAlN/ZrN. The films were deposited with processes developed by the ENEA Brindisi laboratory using a dual magnetron sputtering and HiPPMS physical deposition technique. The wear measures were acquired employing a full factorial design with two factors: i.e., the test conditions (DRY or CRYO) and the pin coatings (not coated NC, coating C1 or C2). The number of tests was 12 since 2 were the replications. Based on preliminary experimental results, it can be stated that there is a type of coating, i.e., TiAlN/ZrN, that allows for high processing speed, high material removal, and a considerable increase in tool life

Study on the State Feedback Selection and Measurement for the Application of an LQRI Secondary Voltage Regulator to a Transmission System

The electrical power system is being significantly affected by the climate change mitigation actions. The power generation, originally centralized, is transitioning towards a more decentralized paradigm due to the coal-fired power plants shut off and the increase in renewable power. Issues in transmission system's voltage control may arise, if the voltage regulation architecture is not modified accordingly. To this aim, in this paper it is investigated the use of a Linear Quadratic Regulator with Integral action (LQRI) for the secondary voltage regulation, aimed at exploiting several reactive power sources as actuators. Being the LQR class of regulators requiring the system state to correctly operate, and being a transmission system a complex system, a critical investigation must be done. In particular, it is needed to identify the variables that are directly measured in a real system, determine if they can be useful for the LQRI state feedback, and finally study the effect of the different possible feedback selection on the regulation performance